Speciation and removal of selenium (IV, VI) from water and wastewaters based on dried activated sludge before determination by flame atomic absorption spectrometry

Volume 4, Issue 01, Pages 36-45, Mar 2021 *** Field: Analytical Environmental Chemistry

  • Mahdiyeh Ghazizadeh, (Corresponding Author) Department of Chemistry, Kerman Branch, Islamic Azad University, Kerman, Iran, P. O. Box 7635131-167
  • Abdollah Abbasloo Department of Chemistry, Kerman Branch, Islamic Azad University, Kerman, Iran
  • Farzaneh Bivar Department of Chemical engineering, Sirjan Branch, Islamic Azad University, Kerman, Iran
DOI: https://doi.org/10.24200/amecj.v4.i01.119
Keywords: Selenium, Water and wastewater, Speciation, Activated sludge, Biosorption, Isotherms

Abstract

In recent decades, large amount of pollutants enter to the environment due to development of technology. Therefore it is necessary to use ecofriendly sorbent to eliminate pollutants. In this research, an dried activated sludge (DAS) was used to decrease Se(IV) pollutant and the effect of operating parameters such as solution pH, the amount of biosorbent, contact time, temperature and initial concentration of selenium were studied. Kinetic data was adjusted to the Langmuir and Freundlich kinetic equations. It was resulted that the Freundlich equation with a correlation coefficient of 0.9956 has the Best match to tetravalent selenium biosorption on DAS. The FT-IR results showed that the biosorption mechanism of selenium tetravalent metal ion on DAS is because of the existence of functional groups on the DAS surface can interact with Se(IV) ions. This study aims to investigate the biosorption capacity of the DAS for tetravalent selenium ions in aqueous solutions.

 

 

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Published
2021-03-30
How to Cite
Ghazizadeh, M., Abbasloo, A., & Bivar, F. (2021). Speciation and removal of selenium (IV, VI) from water and wastewaters based on dried activated sludge before determination by flame atomic absorption spectrometry. Analytical Methods in Environmental Chemistry Journal, 4(01), 36-45. https://doi.org/10.24200/amecj.v4.i01.119
Issue
Vol 4 No 01 (2021): Issue No. One
Section
Original Article

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