Adsorption and determination of Lead in water and human urine samples based on Zn2(BDC)2(DABCO) MOF as polycaprolactone nanocomposite by suspension micro solid phase extraction coupled to UV–VIS spectroscopy

Volume 4, Issue 03, Pages 5-20, Sep 2021 *** Field: Analytical Environmental Chemistry

  • Negar Motakef kazemi, (Corresponding Author) Department of Medical Nanotechnology, Faculty of Advanced Sciences and Technology, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran
  • Masomeh Odar Odar Department of Nanochemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran
Keywords: Lead, Metal organic framework, Polycaprolactone, Nanocomposite, Adsorption, Suspension-micro-solid phase extraction procedure

Abstract

Today, the safety of water resource is the most important challenges which was reported by health and environment organizations. Water pollution can be created by hazardous contaminants of environmental pollutions. Lead as a heavy metal has carcinogenic effects in humans. Metal organic framework (MOF) is a highly porous material with different application. The Zn2(BDC)2(DABCO) is a good candidate of MOF based on zinc metal (Zn-MOF) with potential adsorption/extraction. In this work, Zn2(BDC)2(DABCO) MOF as polycaprolactone (PCL) nanocomposite were applied for lead adsorption/extraction from 50 mL of aqueous solution by ultra-assisted dispersive suspension-micro-solid phase extraction procedure (USA-S- µ-SPE) at pH=8. The samples were characterized by the FTIR, the XRD analysis, the FE-SEM and the BET surface area. The effect of parameters was investigated on lead absorption before determined by UV–VIS spectroscopy. The linear range, the detection limit (LOD) and enrichment factor of adsorbent were obtained 0.05-1 mg L-1, 0.25 μg L-1 and 48.7, respectively (= 0.9992, RSD%=3.65). The absorption capacity of Zn2(BDC)2(DABCO) MOF for 50 mg L-1 of standard lead solution were obtained 133.8 mg g-1 for 0.25 g of adsorbent. The results indicate that this nanocomposite can have a good potential to develop different adsorbents.

 

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Published
2021-09-28
How to Cite
Motakef kazemi, N., & Odar, M. O. (2021). Adsorption and determination of Lead in water and human urine samples based on Zn2(BDC)2(DABCO) MOF as polycaprolactone nanocomposite by suspension micro solid phase extraction coupled to UV–VIS spectroscopy. Analytical Methods in Environmental Chemistry Journal, 4(03), 5-20. https://doi.org/10.24200/amecj.v4.i03.145
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Original Article