Measurement of heavy metals in soil, plants and water samples based on MWCNTs modified with Bis(triethoxysilylpropyl)tetrasulfide by flame atomic absorption spectrophotometry

Volume 5, Issue 01, Pages 49-60, Mar 2022 *** Field:Analytical Method in Environment samples

  • Mohammad Reza Rezaei Kahkha Department of Health Engineering, Zabol University of Medical Sciences, Zabol, Iran
  • Ahmad Salarifar, Corresponding Author, Environmental Engineering Department, Faculty of Natural Resources, Islamic Azad University, Bandar Abbas Branch, Iran
  • Batool Rezaei Kahkha Department of Health Engineering, Zabol University of Medical Sciences, Zabol, Iran
DOI: https://doi.org/10.24200/amecj.v5.i01.167
Keywords: Heavy Metals, Environment sample, Bis(triethoxysilylpropyl)tetrasulfide, Uniform dispersive -micro-solid phase extraction, Flame atomic absorption spectrophotometer

Abstract

Heavy metals (HMs) are considered as the major environmental pollutants that accumulated in soil and plant. Consumption of such contaminated plants by humans and animals would ultimately harm the health of communities. This study aims to evaluate the amount of copper(Co), cadmium(Cd), and lead(Pb) in soil and cultivated plants that are irrigated by the city of Zabol’s wastewater. Also, the heavy metals determined in 20 mL of Zabol’s water based on Bis(triethoxysilylpropyl)tetrasulfide (S4[C3H6Si(OEt)3]2, TEOSiP-TS) modified on MWCNTs as an adsorbent by the uniform dispersive -micro-solid phase extraction (UD-µ-SPE) at optimized pH. In this study, 52 samples including wheat, corn grain, and wild spinach, as well as agricultural soil were selected randomly from three village stations. The concentrations of heavy metals in plants, soils, and water samples were measured using a flame atomic absorption spectrometer (F-AAS).  By optimizing parameters, the linear range (LR) and the detection limit (LOD) of Cu, Cd, and Pb were obtained 1.5-1000 μg L-1, 1-200 μg L-1, 5-1500 μg L-1 and 0.5 μg L-1, 0.25 μg L-1, 1.5 μg L-1, respectively in water samples (RSD%<2). This study indicates that irrigation of agricultural fields using wastewater causes the accumulation of heavy metals in soil and plants.

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Published
2022-03-28
How to Cite
Rezaei Kahkha, M., Salarifar, A., & Rezaei Kahkha, B. (2022). Measurement of heavy metals in soil, plants and water samples based on MWCNTs modified with Bis(triethoxysilylpropyl)tetrasulfide by flame atomic absorption spectrophotometry. Analytical Methods in Environmental Chemistry Journal, 5(01), 49-60. https://doi.org/10.24200/amecj.v5.i01.167
Issue
Vol 5 No 01 (2022): Issue No. One
Section
Original Article

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