Effect of grafted polyurethane on oil spill remediation in the aquatic environment

Volume 6, Issue 02, Pages 42- 54, Jun 2023 *** Field: Analytical Method in Environment chemistry

  • Abdullah Abdul-Lateef Al-Khalaf State Company for Iron and s teel, Mini s try of Indu s try and Modified Minerals, Basrah, Iraq.
  • Hadi Salman Al-Lami, Corresponding Author, Department of Chemi s try, College of Science, University of Basrah, Basrah, Iraq
  • Abbas Fadhil Abbas Department of Chemi s try, College of Science, University of Basrah, Basrah, Iraq
Keywords: Sorption, Chemistry method, Grafted polyurethane, Spill remediation, Aquatic environment

Abstract

The aquatic environment may be seriously harmed when cargo gases, diesel, and their compounds leak or are accidentally spilled onto the water's surface. Oil exploration also leads to water contamination. The remaining oil coats the water's surface, resulting in the formation of a thin emulsion of water and oil. Three novel compounds with long chains of linear alkyl groups were grafted to flexible polyurethane (R-FPU) to clean up oil spills. The sorption testing was thoroughly examined and contrasted with the aid of crude oil, diesel fuel, and water-oil systems. It was found that as compared to ungrafted FPU, the chemical sorption of crude oil and diesel fuel was boosted by modified FPU cubes, while water sorption was reduced by roughly 57%. The sorption competence of the modified FPU was highly correlated with the length of the alkyl chain, with the longer alkyl chain significantly increasing sorption capacity. The results demonstrate that oil may be successfully cleaned using modified FPU cubes.

References

Moatmed, SM; Khedr, MH; El-Dek, S; Kim, H; El-Deen, AG, Highly efficient and reusable superhydrophobic/superoleophobic polystyrene@ Fe3O4 nanofiber membrane for high-performance oil/water separation, J. Environ. Chem. Eng., 7(6) (2019) 103508.‏ https://doi.org/10.1016/j.jece.2019.103508

D.N. Kalbuadi1, D.H. Goenadi1, L.P. Santi1, L.R. Nurtjahja, The potential use of natural clinoptilolite zeolite for crude oil spill removal from seawater, J. Min. Mat. Char. Eng., 7(6) (2019) 446-453.‏ https://doi.org/10.4236/jmmce.2019.76031

E.Y. Yenne, A.Y.B. Anifowose, M.O. Yohanna, An integrated exploration technique for groundwater on a part of the basement complex of southwestern Nigeria, Global J. Geo. Sci., 16 (2018) 45-61.‏ https://doi.org/10.4314/gjgs.v16i1.6

G.O. Aydin, H.B. Sonmez, Hydrophobic poly (alkoxysilane) organogels as sorbent material for oil spill cleanup, Mar. Pollut. Bull., 96 (2015) 155–164. https://doi.org/10.1016 /j.marpolbul.2015.05.0

L. Mohammadi, A. Rahdar, E. Bazrafshan, H. Dahmardeh, M.B. Susan, G.Z. Kyzas, Petroleum hydrocarbon removal from wastewaters: A review, Processes, 8 (2020) 447-483. https://doi.org/10.3390/pr8040447

K. Qiao, W. Tian, J. Bai, L. Wang, J. Zhao, Z. Du, Z., X. Gong, Application of magnetic adsorbents based on iron oxide nanoparticles for oil spill remediation: A review, J. Taiwan Inst. Chem. Eng., 97 (2019) 227-236. https://doi.org/10.1016/J.JTICE.2019.01.029

L. Peng, S. Yuan, G. Yan, P. Yu, Y. Luo, Hydrophobic sponge for spilled oil absorption, J. Appl. Polym. Sci., 131 (2014) 40886 (1-7). https://doi.org/10.1002/app.40886

H. Wang, E. Wang, Z. Liu, D. Gao, R. Yuan, L. Sun, Y. Zhu, A novel carbon nanotubes reinforced superhydrophobic and superoleophobic polyurethane sponge for selective oil-water separation through a chemical fabrication, J. Mater. Chem. A, 3 (2014) 266–273. https://doi.org/10.1039/C4TA03945A

S. Zhao, Z. Wang, W. Zhang, J. Li, Sh. Zhang, A. Huang, Dopamine-mediated pre-crosslinked cellulose/polyurethane block elastomer for the preparation of robust biocomposites, ACS Omega, 3 (2018) 10657-10667. https://doi.org/10.1021/acsomega.8b01694

G. Wang, Z. Zeng, X. Wu, T. Ren, J. Han, Q. Xue, Three-dimensional structured sponge with high oil wettability for the clean-up of oil contaminations and separation of oil–water mixtures, Polym. Chem., 5 (2014) 5942-5948. https://doi.org/10.1039/C4PY00552J

M. Peng, Y. Zhu, H. Li, K. He, G. Zeng, A. Chen, Z. Huang, T. Huang, L. Yuan, G. Chen, Synthesis and application of modified commercial sponges for oil-water separation, Chem. Eng. J., 373 (2019) 213-226. https://doi.org/10.1016/j.cej.2019.05.013

T.A. Sherazi, Graft Polymerization in Encyclopedia of Membranes, Drioli, L. Giorno (eds.), Springer-Verlag Berlin Heidelberg, 2014. https://doi.org/10.1007/978-3-642-40872-4_274-2

A. Bhattacharya, Polymer Grafting and Crosslinking, J. Am. Chem. Soc., 131 (2009) 7204. https://doi.org/10.1021/ja902814m

M. Sadeghi, H. Hosseinzadeh, Studies on graft copolymerization of 2-hydroxyethyl methacrylate onto kappa-carrageenan initiated by ceric ammonium nitrate. J. Chil. Chem. Soc., 55 (2010) 497-502. http://dx.doi.org/10.4067/S0717-97072010000400019

N. Haridharan, D. Sundar, L. Kurrupasamy, S. Anandan, C.‐H. Liu; Jerry J. Wu, Oil spills adsorption and cleanup by polymeric materials: A review, Polym. Adv. Techno., 33 (2022) 1353-1384.‏ http://dx.doi.org/10.1002/pat.5636

A.A. Al-Khalaf, A.F. Abbas, H.S. Al-Lami, Synthesis and characterization of some New 3,3'-(1,4-phenylene) bis (1-(4-aminophenyl) prop-2-en-1-one) amide derivatives, Bas. J. Sci., 40(2) (2022) 437-464. https://doi.org/10.29072/basjs.20220214

H. Li, L. Liu, F. Yang, Hydrophobic modification of polyurethane foam for oil spill cleanup, Mar. Pollut. Bull., 64(8) (2012)1648-165. https://doi.org/10.1016/j.marpolbul.2012.05.039

H. Li, L. Liu, F. Yang, Oleophilic polyurethane foams for oil spill cleanup, Procedia Environ. Sci., 18 (2013) 528-533. https://doi.org/10.1016/j.proenv.2013.04.071

A. Bazargan, J. Tan, G. McKay, Standardization of oil sorbent performance testing, J. Testing Eva., 43 (2015) 1271-1278. https://doi.org/10.1520/JTE20140227

Zhu, J., Wang, Z., Ni, H., Liu, X., Ma, J., & Du, J., A Long-chain alkylation of dialdehyde starch to improve its thermal stability & hydrophobicity, J. Chem., 2016 (2016) 1-7. https://doi.org/10.1155/2016/6095023

L. Peng, H. Li, Y. Zhang, J. Su, P. Yu, Y. Luo, A superhydrophobic 3D porous material for oil spill cleanup, Royal Soc. Chem. (RSC) Adv., 4 (2014) 46470-46475. https://doi.org/10.1039/C4RA06337F

A. Visco, A. Quattrocchi, D. Nocita, R. Montanini, A. Pistone, Polyurethane foams loaded with carbon nanofibers for oil spill recovery: mechanical properties under fatigue conditions and selective absorption in oil/water mixtures, Nanomaterials, 11 (2021) 735-748. https://doi.org/10.3390/nano11030735

Q. Zhu, Y. Chu, Z. Wang, N. Chen, L. Lin, F. Liu, Q. Pan, Robust superhydrophobic polyurethane sponge as a highly reusable oil-absorption material, J. Mater. Chem. A, 1(17) (2013) 5386-5393. https://doi.org/10.1039/C3TA00125C

A.A. Al-Khalaf, H.S. Al-Lami, A.F. Abbas, Flexible polyurethane foam with improved oleophilic and hydrophobic properties for oil spill cleaning, Pet. Sci. Technol., (2022) 1-16. https://doi.org/10.1080/10916466.2022.2118774

L. Kong, Y. Li, F. Qiu, T. Zhang, Q. Guo, X. Zhang, M. Xue, Fabrication of hydrophobic and oleophilic polyurethane foam sponge modified with hydrophobic Al2O3 for oil/water separation, J. Ind. Eng. Chem., 58 (2018) 369-375. https://doi.org/10.1016/j.jiec.2017.09.050

A.M. Tayeb, R. Farouq, O.A. Mohamed, M.A. Tony, Oil spill clean-up using combined sorbents: a comparative investigation and design aspects, Int. J. Environ. Anal. Chem., 100 (2019) 1-13 https://doi.org/10.1080/03067319.2019.1636976

V. Santucci, S. Fiore, Recovery of waste polyurethane from E-waste—Part I: Investigation of the oil sorption potential, Materials, 14 (2021) 6230-6243. https://doi.org/10.3390/ma14216230

Glaser, R., J. Weitkamp, Surface hydrophobicity or hydrophilicity of porous solids, handbook of porous solids, Fourth Edition, Wiley-VCH, Vol.4, p.p 395-400, 2010. https://doi.org/10.1002/9783527618286.ch12

N. Shojaei, F. Aminsharei, H. Abbastabar Ahangar. Application of hydrophobic polymers as solidifiers for oil spill cleanup, Int. J. Environ Sci. Techno., 18 (2021) 1419-1424. https://doi.org/10.1007/s13762-020-02882-y

S. Rasouli, N. Rezaei, H. Hamedi, S. Zendehboudi, X. Duan, Superhydrophobic and superoleophilic membranes for oil-water separation application: A comprehensive review, Mater. Des., 204 (2021) 109599,. https://doi.org/10.1016/j.matdes.2021.109599

L. Xu, Y. Zang, J. Xiao, Y. Wu, Y. Pan, T. Wu, F. Miao, F. Superhydrophobic conjugated microporous polymer-coated sponges: Synthesis and application for highly efficient oil/water separation and the recovery of palladium ions, Sep. Purif. Technol., 261 (2021) 118291. https://doi.org/10.1016/j.seppur.2020.118291

Published
2023-06-29
How to Cite
Al-Khalaf, A., Al-Lami, H., & Abbas, A. (2023). Effect of grafted polyurethane on oil spill remediation in the aquatic environment. Analytical Methods in Environmental Chemistry Journal, 6(02), 42- 54. https://doi.org/10.24200/amecj.v6.i02.238
Section
Original Article